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(A) Plot of Mn and Mw/Mn (PDI) vs monomer conversion for the polymerizations of MOEPA by using TBD as the catalyst and benzyl alcohol as the initiator, obtained from a combination of GPC and 31P NMR analyses. Monomer : initiator ratios were 100 : 1 and 50 : 1. (B) Kinetic plots of ln[([M]0−[M]eq)/([M]−[M]eq)] vs time, obtained from 31P NMR spectroscopy data.
