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Stepwise aggregation-deprotonation (StepAD) mechanism for the encapsulation of HgII by the 3SCC, (BabyL9C)3. HgII reacts in a fast step to form [HgII]S(BabyL9C)2. Formation of [HgII]S(BabyL9C)2(H-BabyL9C) is the rate-limiting association and, depending on pH, rapidly converts to [HgII]S(BabyL9C)3−. Figure was reproduced from ref. [125] with permission of the copyright holders.
