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Catalytic Hydrogenations by 1 with H2
| Precatalyst | Substrate | Product | TOF (h−1) |
|---|---|---|---|
| 1 | Ethylenea | Ethane | 15 |
| 1 | Styrenea | Ethylbenzene | 0.27 |
| 1 | Phenylacetyleneb | Ethylbenzene | 0.16 |
Conditions: Room temperature, 0.01 M 1, 1 atm H2, and 0.01 M ferrocene as an internal integration standard in d6-benzene.
0.3 M substrate,
0.29 M substrate.
As determined by 1H NMR spectroscopy at > 95% product.
