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. 2013 Jul 5;13(7):8640–8668. doi: 10.3390/s130708640

Table 5.

Overview of the optical and fibre optic sensing for Color, COD and BOD detection.

Parameter Material Optical Range (nm) Detection Range (mg/L) Sensing Method Response Time Advantageous/Limitation Application Ref.
Color Direct determination 514.5 1000 Optical (Absorption-Based) 5 min Sample handling Dyed fibres [76]
Color Leather Dye Mixture Color (Red-Blue-Yellow) 400 to 900 Differentiate mixture of color, errors5.6 to10.7 and 6.9 to12.5% Optical (Absorption-Based) Once the PLSR method is optimized, new samples can be determined. Sample handling Leather dye detection [77]
Color Indigo Solution 635 800 to 12000, errors 0.5% Optical (Absorption-Based) 15 min Real time monitoring Denim yarn [78]
Color Red, Amber, Blue solution 300 to 900 36 to1000, errors 1% FOS 10 spectra were taken and averaged Sample handling Textile industry-dye bath [79]
COD Direct determination 254 & 356 0 to360 ± 1.8 Optical (Absorption-Based) ∼2 min Sample handling Printing and dyeing wastewater [80]
COD Direct determination excitation wavelengths from 250 to 600 13 to 456 ± 6% Optical (Synchronous Fluorescence) Standard laboratory device. Sample handling Waste water from urban and non-urban area [3]
COD Phthalatehydrogen potassium for oxidation near-infrared (NIR) transmission & ultraviolet absorbance (254) 5 to 400 ± 2% Optical (Absorption-Based) --- Real time monitoring Organic pollutant [24]
COD Potassium hydrogen phthalate solution 200 to 720 30 to 1000 ± 1% Optical 5 min Real time monitoring Lakes, river or waste water [81]
COD Direct determination UV-220 & 254 emission spectra 300 to 550 1.6 to 20.6 ± 3% Optical -- Real time monitoring Urban river water [82]
COD Direct determination 258 to 380& UV 0 to 350 ± 6% FOS 62 s Real time monitoring Wastewater quality monitoring [83]
BOD Direct determination 220 to 1,100; excitation/emission 280/350 0 to 400 Optical (Absorption and Fluorescence Technique) Standard laboratory device. Sample handling Sewage sample [84]
BOD Direct determination 190 to 900 100 to 10,000 Optical Standard laboratory device. Sample handling Dirty water, slurry water [25]
BOD Direct determination Excitation 250 to 600 nm 5.2 to 208 ± 8% Optical (Synchronous Fluorescence) Standard laboratory device. Sample handling Waste water from urban and non-urban area [3]
BOD Direct Determination 220 to 1,100 ;excitation λ 250 to 400 nm; emission λ 300 to 550 nm 0.5 to 25.4 ± 3% Optical (Absorption and Flurescence) Standard laboratory device Sample handling Urban river water [82]
BOD Direct determination 254 nm and fluorescence intensity 270 ∼ 300, 310 ∼ 370, 370 ∼ 400 & 400 ∼ 530 Waste water = 6.5 to 139.9 ± 10%; River water = 1.3 to 1.9 ± 22% Optical (Absorption and Synchronous Flurescence) Predict BOD by using multiple regression analysis Sample handling River water samples wastewater treatment plant effluent [28]
BOD Tris(4,7-diphenyl-l,lOphenanthroline) ruthenium(II) perchlorate; Trichosporon cufaneum 480, excitation 610 nm. 3 to 110 ± 4% FOS 3–10 min Rapid feedback signal, very low costs Sewage plant effluent and municipal sewage [85]
BOD Pseudomonas putida Used current 1 to 10 ± 20% FOS (Fluorescenc-Based) 15 min Long-term stability, no calibration drift occurs, not affected by heavy metal ions and chlorine concentration River Water [86]
BOD Ru(I1) polypyridyl complex Red-excitation, Blue-emmision -- FOS -- Real time monitoring Waste water [87]
BOD Tris(4,7-diphenyl-1, 10-phenanthroline) ruthenium(II) dye;B. subtilis, &activated sludge Four LED blue light (460 nm) 25 to 60 ± 14% FOS (Fluorescenc-Based) 15–30 min (by batch) Sample handling GGA, domestic and synthetic WW, OECD [88]
BOD 4,7-diphenyl-1,10-phenanthroline Ru(dpp)32+; B. licheniformis, D. marisand M.marinus Blue LED (465 nm) 0.2 to 40 FOS (Fluorescenc-Based) 3.2 min without dramatically affected by sodium chloride Seawater [89]