Table 3.
Kinetics parameters and the limit of detection (LOD).
| DTBU: HEg3UT = 1: x | Polymerization Time [s] | Association Rate Constant Ka [Ms−1] | Dissociation Rate Constant Kd [s−1] | Association Constant KA [M] | LOD [ppt] |
|---|---|---|---|---|---|
| 10 | 300 | 1.76E + 06 | 1.02E − 03 | 1.73E + 09 | 5.7 |
| 10 | 600 | 4.32E + 05 | 4.19E − 04 | 1.03E + 09 | 17.7 |
| 100 | 300 | 8.02E + 05 | 1.76E − 04 | 4.56E + 09 | 6.0 |
| 100 | 600 | 9.21E + 03 | 4.16E − 04 | 2.21E + 07 | 8.7 |
| 1,000 | 300 | 1.24E + 06 | 4.53E − 04 | 2.74E + 09 | 22.2 |
| 1,000 | 600 | 1.07E + 04 | 2.66E − 04 | 4.02E + 07 | 39.5 |
| 10,000 | 300 | 1.53E + 05 | 5.02E − 05 | 3.05E + 09 | 124.4 |
| 1,000 | 600 | 2.44E + 05 | 6.90E − 05 | 3.54E + 09 | 638.3 |
| 100,000 | 300 | 2.81E + 05 | 1.08E − 04 | 2.60E + 09 | 104.2 |
| 100,000 | 600 | 4.17E + 05 | 5.32E − 05 | 7.84E + 09 | 859.1 |