Table 1.
Species | pKa1 ±σ |
Δa1Ha ±σ |
Δa1Sb ±σ |
pKa2 ±σ |
Δa2H ±σ |
Δa2S ±σ |
pKa3 ±σ |
Δa3H ±σ |
Δa3S ±σ |
Ref. |
---|---|---|---|---|---|---|---|---|---|---|
MnIITE-2-PyP | 11.75 ± 0.01 |
- | - | - | - | - | - | - | - | This work |
MnIITE-3-PyP | 12.04 ± 0.03 |
- | - | - | - | - | - | - | - | This work |
MnIITnBu-2-PyP | 11.99 ± 0.03 |
59 ± 2 |
−32 ± 7 |
- | - | - | - | - | - | 31 |
MnIIITE-2-PyP | 10.89 ± 0.01 |
49 ± 1 |
−44 ± 3 |
11.62 ± 0.02 |
48 ± 3 |
−62 ± 11 |
- | - | - | This work |
MnIIITE-3-PyP | 11.57 ± 0.01 |
51 ± 3 |
−51 ± 9 |
12.70 ± 0.09 |
51 ± 3 |
−72 ± 11 |
- | - | - | This work |
MnIIITnBu-2-PyP | 11.36 ± 0.01 |
60 ± 2 |
−16 ± 8 |
12.33 ± 0.01 |
49 ± 3 |
−67 ± 8 |
- | - | - | 31 |
MnIVTE-2-PyP | - | - | - | - | - | - | 11.14 ± 0.02 |
52 ± 3 |
−37 ± 11 |
This work |
MnIVTE-3-PyP | - | - | - | - | - | - | 11.99 ± 0.04 |
50 ± 6 |
−59 ± 19 |
This work |
MnIVTnBu-2-PyP | - | - | - | - | - | - | 11.78 ± 0.02 |
48 ± 2 |
−63 ± 7 |
31 |
Reaction enthalpies are given in kJ mol−1.
Reaction entropies are given in J K−1 mol−1.