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. Author manuscript; available in PMC: 2014 Jul 17.
Published in final edited form as: J Am Chem Soc. 2013 Jul 2;135(28):10198–10201. doi: 10.1021/ja402645y

Table 1.

Spectroscopic comparison of FeIII(TMC)-peroxo complexes (S = 5/2) in CH3CN

λmax,
nm		 ΔEQ,
mm/s		 δ,
mm/s		 D,
cm−1 		E/D Pre-edge
area		 ref
2 835 −0.92 0.58 −0.91 0.28 17.9 7a
3 520 0.50 0.47 1.3 0.18 14.4 *
5 500 0.20 0.51 2.5 0.097 22.4 7a
*

this work.