Table 1.
M:I 20:1 | M:I 200:1 | ||||||||
---|---|---|---|---|---|---|---|---|---|
Monomer | Peptide Sequence | Percent Conversiona | DPb | Mw/Mn b | Percent Conversiona | DPb | Mw/Mn b | ||
1 | NorGFPLI | 100 | 15 | 1.02 | 100 | 191 | 1.31 | ||
2 | 100 | 22 | 1.03 | 100 | 194 | 1.02 | |||
3 | 100 | 23 | 1.06 | 100 | 187 | 1.03 | |||
4 | 100 | 15 | 1.10 | 96 | 155 | 1.09 | |||
5 | 100 | 23 | 1.02 | 100 | 125 | 1.00 | |||
6 | 100 | 15 | 1.19 | 83 | 62 | 1.02 | |||
7 | 100 | 19 | 1.05 | 100 | 179 | 1.02 | |||
8 | 100 | 20 | 1.03 | 100 | 159 | 1.04 | |||
9 | 100 | 15 | 1.04 | 76 | 102 | 1.01 | |||
10 | 100 | 22 | 1.05 | 100 | 165 | 1.03 | |||
11 | 100 | 21 | 1.10 | 100 | 182 | 1.20 | |||
12 | 100 | 16 | 1.13 | 100 | 189 | 1.10 | |||
13 | 16 | - | - | - | - | - | |||
14 | 100 | 20 | 1.10 | 100 | 188 | 1.02 | |||
15 | 100 | NDc | 100 | NDc | |||||
16 | 100 | NDc | 100 | NDc | |||||
17 | 100 | 19 | 1.13 | 100 | 175 | 1.03 | |||
18 | 100 | 18 | 1.11 | 100 | 193 | 1.04 | |||
19 | 100 | 30 | 1.03 | 98 | 134 | 1.36 | |||
20 | 100 | 17 | 1.24 | 100 | 182 | 1.00 | |||
21 | 100 | 12 | 1.05 | 87 | 132 | 1.20 | |||
22 | 100 | 14 | 1.04 | 98 | 193 | 1.03 | |||
23 | 100 | 15 | 1.04 | 100 | 157 | 1.02 | |||
24 | 100 | 15 | 1.04 | 100 | 163 | 1.31 | |||
25 | 100 | NDc | 100 | NDc | |||||
26 | 100 | 25 | 1.02 | 99 | 216 | 1.02 | |||
27 | 100 | 14 | 1.22 | 100 | 187 | 1.02 | |||
28 | 100 | 17 | 1.10 | 100 | 182 | 1.03 | |||
29 | 100 | 20 | 1.20 | 100 | 192 | 1.02 | |||
30 | 100 | NDc | 100 | NDc | |||||
31 | 22 | - | - | - | - | - | |||
Average | 18 ± 4 | 1.083 ± 0.066 | 167 ± 34 | 1.06 ± 0.08 |
As determined by 1H NMR.
As determined by SEC-MALS, 0.05 M LiBr in DMF.
Could not determine by SEC-MALS.