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. Author manuscript; available in PMC: 2014 May 28.
Published in final edited form as: Polym Chem. 2013 May 28;41:3929–3933. doi: 10.1039/C3PY00526G

Table 1.

Polymerization of pentapeptide norbornyl monomers.



M:I 20:1 M:I 200:1


Monomer Peptide Sequence Percent Conversiona DPb Mw/Mn b Percent Conversiona DPb Mw/Mn b
1 NorGFPLI 100 15 1.02 100 191 1.31
2 graphic file with name nihms485737t1.jpg 100 22 1.03 100 194 1.02
3 graphic file with name nihms485737t2.jpg 100 23 1.06 100 187 1.03
4 graphic file with name nihms485737t3.jpg 100 15 1.10 96 155 1.09
5 graphic file with name nihms485737t4.jpg 100 23 1.02 100 125 1.00
6 graphic file with name nihms485737t5.jpg 100 15 1.19 83 62 1.02
7 graphic file with name nihms485737t6.jpg 100 19 1.05 100 179 1.02
8 graphic file with name nihms485737t7.jpg 100 20 1.03 100 159 1.04
9 graphic file with name nihms485737t8.jpg 100 15 1.04 76 102 1.01
10 graphic file with name nihms485737t9.jpg 100 22 1.05 100 165 1.03
11 graphic file with name nihms485737t10.jpg 100 21 1.10 100 182 1.20
12 graphic file with name nihms485737t11.jpg 100 16 1.13 100 189 1.10
13 graphic file with name nihms485737t12.jpg 16 - - - - -
14 graphic file with name nihms485737t13.jpg 100 20 1.10 100 188 1.02
15 graphic file with name nihms485737t14.jpg 100 NDc 100 NDc
16 graphic file with name nihms485737t15.jpg 100 NDc 100 NDc
17 graphic file with name nihms485737t16.jpg 100 19 1.13 100 175 1.03
18 graphic file with name nihms485737t17.jpg 100 18 1.11 100 193 1.04
19 graphic file with name nihms485737t18.jpg 100 30 1.03 98 134 1.36
20 graphic file with name nihms485737t19.jpg 100 17 1.24 100 182 1.00
21 graphic file with name nihms485737t20.jpg 100 12 1.05 87 132 1.20
22 graphic file with name nihms485737t21.jpg 100 14 1.04 98 193 1.03
23 graphic file with name nihms485737t22.jpg 100 15 1.04 100 157 1.02
24 graphic file with name nihms485737t23.jpg 100 15 1.04 100 163 1.31
25 graphic file with name nihms485737t24.jpg 100 NDc 100 NDc
26 graphic file with name nihms485737t25.jpg 100 25 1.02 99 216 1.02
27 graphic file with name nihms485737t26.jpg 100 14 1.22 100 187 1.02
28 graphic file with name nihms485737t27.jpg 100 17 1.10 100 182 1.03
29 graphic file with name nihms485737t28.jpg 100 20 1.20 100 192 1.02
30 graphic file with name nihms485737t29.jpg 100 NDc 100 NDc
31 graphic file with name nihms485737t30.jpg 22 - - - - -
Average 18 ± 4 1.083 ± 0.066 167 ± 34 1.06 ± 0.08
a

As determined by 1H NMR.

b

As determined by SEC-MALS, 0.05 M LiBr in DMF.

c

Could not determine by SEC-MALS.