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. Author manuscript; available in PMC: 2014 May 28.
Published in final edited form as: Polym Chem. 2013 May 28;41:3929–3933. doi: 10.1039/C3PY00526G

Table 2.

Polymerization of additional pentapeptide modified norbornene monomers.


M:I 20:1

Monomer Peptide Sequence Percent Conversiona DPb Mw/Mn b
32 NorGKGKGK 71 590c 1.01
33 NorAhaKGKGK 100 390c 1.01
34 NorGK*GK*GK* 100 11 1.01
35 NorAhaK*GK*GK* 100 9 1.01
36 Nor(GFPLI)3 100 18 1.04
37 Nor(GFPLI)6 100 18 1.04
38 NorGKQLISGSGS 100 21 1.04
39 NorGSGSGKQLIS 100 19 1.02
a

As determined by 1H NMR.

b

As determined by SEC-MALS, 0.05 M LiBr in DMF

c

Poor performance on SEC-MALS.

*

denotes Boc protecting group.

Aha = alkyl-linker as shown in Figure 3