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. 2013 Sep 16;8(9):e75096. doi: 10.1371/journal.pone.0075096

Table 1. Melting temperature (Tm), enthalpy change (ΔH), and heat capacity change (ΔCp) are determined by CD and calculated Gibbs free energy change (ΔGU) in unfolding state at 25°C for the CT in different mediaa.

Sample Tm (°C) ΔH (kJ.mol−1) ΔGU (kJ.mol−1) Δ Cp (kJ.mol−1.C−1)
Buffer 42.0 424 18.2 10.0
Buffer+AAPJ 40.0 299 11.7 7.1
1 M TEAP 62.0 842 57.4 14.0
1 M TEAP+AAPJ 61.8 840 57.2 13.6
1 M TEAS 57.0 688 44.3 12.1
1 M TEAS+AAPJ 51.1 613 33.7 12.0
1 M [Bmim][Cl] 55.8 652 43.6 11.7
1 M [Bmim][Cl]+AAPJ 45.4 546 26.9 12.0
1 M [Mim][Cl] 45.0 428 20.8 9.5
1 M [Mim][Cl]+AAPJ 43.0 394 17.6 9.2
a

The estimated relative uncertainties in (ΔH), (ΔCp) and (ΔGU) are around 2% of the reported values.