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. Author manuscript; available in PMC: 2014 Sep 20.
Published in final edited form as: J Org Chem. 2013 May 3;78(18):8927–8955. doi: 10.1021/jo400159y

Scheme 14.

Scheme 14

Ligand-promoted ortho-C–H functionalization of phenethyl alcohols: (a) olefination137 and (b) carbonylation.139 (c) General catalytic cycle C–H carbonylation via Pd(II)/Pd(0) catlaysis; Nu = generic nucleophile.