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. Author manuscript; available in PMC: 2013 Sep 22.
Published in final edited form as: Biochemistry. 2011 Oct 27;50(46):10150–10158. doi: 10.1021/bi2009618

Figure 4.

Figure 4

Reaction space for the CI formation in TcTS mechanism. The axes are the Pauling bond orders from the anomeric C to the leaving group (nLG) and the nucleophile (nNU). The reactant, TS and product configuration are shown in the bottom left, top left and top right, respectively.