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. Author manuscript; available in PMC: 2014 Jul 29.
Published in final edited form as: Angew Chem Int Ed Engl. 2013 Jun 18;52(31):8156–8159. doi: 10.1002/anie.201304035

Scheme 3.

Scheme 3

Representative cases of efficient and enantioselective NHC-Cu-catalyzed ECA reactions with Et3Al and non-aryl-substituted enones as well as with Me3- and (iBu)3Al reagents.