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. Author manuscript; available in PMC: 2013 Oct 1.
Published in final edited form as: Angew Chem Int Ed Engl. 2012 May 23;51(27):6618–6621. doi: 10.1002/anie.201202694

Scheme 6.

Scheme 6

Representative examples demonstrate the utility of the NHC–Cu-catalyzed method for enantioselective synthesis of homopropargyl amines; o-NBSH= o-nitrobenzenesulfonylhydrazide.