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. Author manuscript; available in PMC: 2014 Sep 18.
Published in final edited form as: J Am Chem Soc. 2013 Sep 5;135(37):13914–13926. doi: 10.1021/ja4067404

Table 1.

Comparative Dynamic Hyperpolarizabilities Determined for RuPZn, Holo-SCPZN-1 and Holo-SCPZN-2 as a Function Incident Irradiation Wavelength

βλ (10−30 esu)
Chromophore 800 nm 1300 nm 1340 nm
RuPZn13 <50 5100 Not measured
holo-SCRPZ-1 200 ± 50 1200 ± 200 3100 ± 1000
holo-SCRPZ-2 550 ± 150 1000 ± 300 3300 ± 1000

Experimental conditions: RuPZn: acetonitrile solvent, see ref13; holo-SCRPZ-1: 50 mM phosphate buffer, 5% isopropanol, 150 mM NaCl, pH 7.5; holo-SCRPZ-2: 50 mM phosphate buffer, 150 mM NaCl, pH 7.5.