Table 1.

Raman metrics

Part A. Raman band center wavenumber (BCW) and relative intensity (RI).
Groups	Phospate ν1		Proline and Hydroxyproline		Phenylalanine		Carbonate	Subbands in amide I region
	BCW (cm−1)	RI (a.u.)	BCW (cm−1)	RI (a.u.)	BCW (cm−1)	RI (a.u.)	BCW (cm−1)	BCW (cm−1)	RI (a.u.)
Control	957.99±0.01	17.43±0.22	853.09±0.07 874.28 ±0.09	1.84±0.11	1001.48±0.05	0.23±0.02	1070.74±0.15	1665.14±0.63 1685.61±0.40	1.27±0.38 0.50±0.18
XRT	958.26±0.06	17.55±0.17	852.64±0.39 873.63±0.79	1.66±0.08	1001.50±0.03	0.21±0.02	1070.60±0.21	1665.89±0.69 1686.73±0.56	1.09±0.31 0.30±0.11
AMF-XRT	958.05±0.05	17.19±0.22	852.92±0.10 874.07±0.24	1.71±0.07	1001.59±0.16	0.21±0.02	1070.74±0.15	1666.32±0.13 1686.45± 0.54	1.20±0.28 0.33±0.12

Part B. Derived spectroscopic parameters.
Groups	Mineral crystallinity FWHM ${\mathrm{PO}}_4^{3-}$ ν1 (958 cm−1)	Carbonate/phosphate 1070 cm−1/958 cm−1	Phosphate/phenylalanine 958 cm−1/1002 cm−1	Phosphate/(proline and hydroxyproline) 958 cm−1/(854+873) cm−1	Collagen cross-link (matrix maturity) 1665 cm−1/1685 cm−1
Control	17.21±0.08	0.21±0.01	76.16±6.49	9.51±0.51	2.83±1.30
XRT	17.10±0.09	0.19±0.01	85.66±7.36	10.62±0.51	4.12±2.03
AMF-XRT	17.23±0.09	0.21±0.01	81.44±5.80	10.07±0.39	4.08±1.77