| in DMSO-d6 [40] | In CDCl3 [27] | ||||
|---|---|---|---|---|---|
|
|
|||||
| Position | mult. | δc (75 MHz) | δH (J in Hz) (300 MHz) | δc (100 MHz) | δH (J in Hz) (400 MHz) |
|
| |||||
| 2 pro S | CH2 | 69.84 | 3.92, dd (10.2,10.2) | 70 | 4.01 dd (10.3, 10.3) |
| 2 pro R | 4.23, br d (10.2) | 4.39 ddd (10.3, 3.2, 1.8) | |||
| 3 | CH | 31.01 | 3.29, m | 31.7 | 3.52, m |
| 4 pro S | CH2 | 30.09 | 2.69, dd (15.6, 4.2) | 30.6 | 2.83 ddd (15.7, 5.3, 1.8) |
| 4 pro R | 2.88, dd (15.6, 10.2) | 2.99 dd (15.6, 11.0) | |||
| 5 | CH | 129.22 | 6.81, d (8.2) | 129.2 | 6.81, d (8.2) |
| 6 | CH | 108.21 | 6.27, d (8.2) | 108.7 | 6.33, d (8.2) |
| 7 | C | 151.33 | 151.9 | ||
| 8 | C | 109.15 | 109.15 | ||
| 9 | C | 149.36 | 149.3 | ||
| 10 | C | 114.84 | 114.84 | ||
| 1′ | C | 117.58 | 120.0 | ||
| 2′ (OH) | C | 155.94 | 9.35, s | 154.4 | 7.68 |
| 3′ | CH | 102.63 | 6.32, d (1.3) | 103.1 | 6.46, d (2.2) |
| 4′ (OH) | C | 156.97 | 9.08, s | 155.2 | 7.48 |
| 5′ | CH | 106.41 | 6.18, dd (8.2, 1,3) | 108.0 | 6.39, dd (8.2, 2.2) |
| 6′ | CH | 127.67 | 6.84, d (8.2) | 128.4 | 6.91, d (8.2) |
| 2″ | C | 75.33 | 75.6 | ||
| 3″ | CH | 129.30 | 5.63, d (9.9) | 128.9 | 5.55, d (9.90) |
| 4″ | CH | 116.52 | 6.53, d (9.9) | 116.9 | 6.64, d (9.90) |
| 5″ | CH3 | 27.33 | 1.33, s | 27.6 | 1.40, s |
| 6″ | CH3 | 27.45 | 1.33, s | 27.8 | 1.42, s |
The 1H chemical shifts (δ) were expressed in ppm with reference to the residual solvent signal (DMSO-d5, 2.500 ppm and CDCl3, 7.250 ppm relative to the TMS scale), and coupling constants (J) were given in Hertz. In CDCl3 at 300, 400 MHz, resonances of the protons H-5′ and H-6 are overlapping (bold font).