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. Author manuscript; available in PMC: 2014 Jun 5.

Published in final edited form as: J Am Chem Soc. 2013 May 24;135(22):8213–8221. doi: 10.1021/ja403165u

Kinetic time course of the dehydrogenation of cyclohexanone ( ) to phenol (■), with cyclohexenone ( ) observed as the intermediate. Reaction conditions: [cyclohexanone] = 1.0 M (0.5 mmol), [Pd(TFA)₂] = 0.05 M (0.025 mmol), [2-Me₂Npy] = 0.1 M (0.05 mmol), [TsOH] = 0.2 M (0.1 mmol), DMSO for total volume of 0.5 mL, 1 atm O₂, 80 °C. Figure adapted from reference 3a.

Inline graphic — Kinetic time course of the dehydrogenation of cyclohexanone ( ) to phenol (■), with cyclohexenone ( ) observed as the intermediate. Reaction conditions: [cyclohexanone] = 1.0 M (0.5 mmol), [Pd(TFA)₂] = 0.05 M (0.025 mmol), [2-Me₂Npy] = 0.1 M (0.05 mmol), [TsOH] = 0.2 M (0.1 mmol), DMSO for total volume of 0.5 mL, 1 atm O₂, 80 °C. Figure adapted from reference 3a.