Table 1.

Cross-Coupling of Various Aryl Sulfamates with Primary Aminomethyltrifluoroborate 1

entry	product yield(%)b/conversion(%)c
1d	2a, 93(93)h/100
2e	2b, 85/90
3d	2c,13b/27
4d	2d, 38b/38
5d	2e, 23b/25
6d	2f, 90/100
7d	2g, 88/100
8d	2h, 93/100
9f	2i, 72/75 89/98g
10d	2j, 87/100
11e	2k, 60/80
12e	2l, 76/100

^aReaction conditions: 1.0 equiv of aryl sulfamate, 1.05 equiv of trifluoroborate, 4 mol % XPhos-Pd-G2, K₂CO₃, t-BuOH/H₂O (1:1, 0.5 M), 85 °C, 3 h.

^bisolated yield.

^ccalculated by ¹H NMR with 30 μL of CH₂Cl₂.

^d3 equiv K₂CO₃.

^e5 equiv K₂CO₃.

^f7 equiv K₂CO₃.

^gn-PrOH/H₂O.

^h3 mmol of sulfamate, 2 mol % XPhos-Pd-G2, 3 equiv K₂CO₃, t-BuOH/H₂O (1:1, 0.5 M), 85 °C, 18 h.