TABLE 1.
Detected TRIR bands
| Wave number | Bandwidtha | Time constant | ΔIb | Δϵc |
|---|---|---|---|---|
| cm−1 | cm−1 | μs | mOD | m−1 cm−1 |
| 2063 | 10.0 (±0.1) | Rise <0.05 | 5.08 (±0.49) | 882 (±85) |
| Decay 1.6 (±0.1) | −4.65 (±0.39) | −807 (±68) | ||
| 2061 | 35.0 (±0.9) | Rise <0.05 | 1.33 (±0.17) | 231 (±30) |
| Decay 1.7 (±0.2) | −1.07 (±0.13) | −186 (±23) | ||
| 1965 | 5.9 (±0.0) | Rise <0.05 | −20.29 (±1.57) | −3523 (±273) |
| 1962 | 16.6 (±0.2) | Rise <0.05 | −5.23 (±0.48) | −908 (±83) |
| 1750 | 6.5 (±0.5) | Rise 15.7 (±6.6) | 0.06 (±0.00) | 19 (±0) |
| 1749 | 12.1 (±1.2) | Rise <0.05 | 0.28 (±0.01) | 90 (±3) |
| Decay 1.1 (±0.4) | −0.10 (±0.01) | −32 (±3) | ||
| 1745 | 11.1 (±0.4) | Rise <0.05 | −0.21 (±0.03) | −67 (±10) |
| Rise 15.6 (±9.9) | −0.04 (±0.01) | −13 (±3) | ||
| 1738 | 11.7 (±0.7) | Rise <0.05 | −0.08 (±0.01) | −26 (±3) |
| Decay 0.7 (±0.5) | 0.06 (±0.01) | 19 (±3) | ||
| 1701 | 11.4 (±0.4) | Rise <0.05 | −0.11 (±0.01) | −156 (±14) |
| 1689 | 9.7 (±0.3) | Rise <0.05 | −0.09 (±0.01) | −127 (±14) |
| 1678 | 10.6 (±0.4) | Rise <0.05 | 0.29 (±0.02) | 410 (±28) |
| Decay 1.9 (±0.8) | −0.29 (±0.02) | −410 (±28) | ||
| 1670 | 9.4 (±0.2) | Rise <0.05 | 0.79 (±0.07) | 1117 (±99) |
| Rise 2.0 (±0.2) | 0.31 (±0.08) | 438 (±113) | ||
| 1666 | 8.4 (±0.3) | Rise <0.05 | −0.85 (±0.07) | −1202 (±99) |
| Decay 2.6 (±0.3) | 0.85 (±0.07) | 1202 (±99) | ||
| 1662 | 9.5 (±0.1) | Rise <0.05 | 0.55 (±0.05) | 778 (±71) |
| 1656 | 23.1 (±4.4) | Rise 38.7 (±15.2) | −0.16 (±0.01) | −226 (±14) |
| 1655 | 10.6 (±0.2) | Rise <0.05 | 0.56 (±0.04) | 792 (±57) |
| Decay 1.8 (±0.2) | −0.56 (±0.04) | −792 (±57) | ||
| 1645 | 15.5 (±1.1) | Rise 0.7 (±0.2) | −0.19 (±0.02) | −269 (±28) |
| 1642 | 20.3 (±1.4) | Rise <0.05 | 0.41 (±0.02) | 580 (±28) |
| Decay 82.9 (±11.4) | −0.33 (±0.01) | −467 (±14) | ||
| 1627 | 16.5 (±1.0) | Rise <0.05 | 0.24 (±0.02) | 339 (±28) |
| 1616 | 8.6 (±0.5) | Rise <0.05 | 0.16 (±0.01) | 226 (±14) |
| Decay 14.3 (±2.7) | −0.16 (±0.01) | −226 (±14) | ||
| 1612 | 14.5 (±0.6) | Rise <0.05 | 0.17 (±0.01) | 240 (±14) |
| Decay 1.0 (±0.1) | −0.10 (±0.01) | −141 (±14) | ||
| 1592 | 10.6 (±0.1) | Rise <0.05 | −0.17 (±0.01) | −94 (±6) |
| 1577 | 16.8 (±0.1) | Rise <0.05 | −0.42 (±0.02) | −233 (±11) |
| Decay 2.3 (±0.6) | 0.20 (±0.00) | 111 (±1) | ||
| 1559 | 21.4 (±0.2) | Rise <0.05 | −0.52 (±0.02) | −289 (±11) |
| Decay 12.5 (±5.3) | 0.26 (±0.02) | 144 (±11) | ||
| 1549 | 15.2 (±0.5) | Rise 2.4 (±0.3) | 0.59 (±0.01) | 328 (±6) |
| 1545 | 10.6 (±0.1) | Rise <0.05 | −0.68 (±0.02) | −378 (±11) |
| 1538 | 11.2 (±0.0) | Rise <0.05 | 0.48 (±0.02) | 267 (±11) |
| Decay 3.0 (±0.4) | −0.48 (±0.02) | −267 (±11) | ||
| 1533 | 11.4 (±0.0) | Rise <0.05 | −1.17 (±0.02) | −650 (±11) |
| 1524 | 20.3 (±0.5) | Rise <0.05 | −0.59 (±0.02) | −328 (±11) |
| Decay 1.9 (±0.5) | 0.14 (±0.01) | 78 (±6) | ||
| 1509 | 15.5 (±0.3) | Rise <0.05 | 0.14 (±0.00) | 78 (±1) |
a Full width at half-maximum is given.
b Intensity change is shown.
c Molar extinction coefficient change is as follows: Δϵ = ΔI/([P]·0.8·l); where [P] is the protein concentration used in the experiment; l is the optical path length. The CO photolysis yield (0.8) was taken into account.