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. Author manuscript; available in PMC: 2014 Sep 4.
Published in final edited form as: J Am Chem Soc. 2013 Aug 22;135(35):13168–13184. doi: 10.1021/ja406608u

Table 4. Cobalt K-edge parameters for bis(arylimidazol-2-ylidene)pyridine and bis(imino)pyridine cobalt halide and methyl compounds.

Compound Pre-edge Energy (eV) Pre-edge Intensity Aa Pre-edge Intensity Bb Temperature (K)
(iPrCNC)CoBr 7709.8 33(3) 42(3) 10
7711.8 17(4) 7(1) 10
(iPrCNC)CoCH3 7709.7 29.8(6) 37.6(8) 10
7711.2 5.8(8) 7(2) 10
(iPrPDI)CoCl 7709.3 14.1(9) 18(1) 10
(iPrPDI)CoCH3 7709.3 13(1) 16(2) 10
a

Fit using method described in reference 72.

b

Fit using method described in reference 73.