Table 4. Cobalt K-edge parameters for bis(arylimidazol-2-ylidene)pyridine and bis(imino)pyridine cobalt halide and methyl compounds.
Compound | Pre-edge Energy (eV) | Pre-edge Intensity Aa | Pre-edge Intensity Bb | Temperature (K) |
---|---|---|---|---|
(iPrCNC)CoBr | 7709.8 | 33(3) | 42(3) | 10 |
7711.8 | 17(4) | 7(1) | 10 | |
(iPrCNC)CoCH3 | 7709.7 | 29.8(6) | 37.6(8) | 10 |
7711.2 | 5.8(8) | 7(2) | 10 | |
(iPrPDI)CoCl | 7709.3 | 14.1(9) | 18(1) | 10 |
(iPrPDI)CoCH3 | 7709.3 | 13(1) | 16(2) | 10 |
Fit using method described in reference 72.
Fit using method described in reference 73.