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. Author manuscript; available in PMC: 2014 Sep 11.
Published in final edited form as: J Am Chem Soc. 2013 Aug 28;135(36):13222–13234. doi: 10.1021/ja308229p

Table 1.

Selected Examples of MOFs with highest gas uptake capacities.

MOF BET Surface
area (m2/g)
Pore volume
(cm3g−1)
Pressur
e (bar)
Excess H2 uptake at 77 K
(wt%)/Volumetric (g/L)
Excess H2 uptake
at 298 K (wt%)
Excess CH4 uptake at 298
K (wt %)/Volumetric (g/L)
Zn-
TBCPPM23 2718 1.46 80 5.8/39 1.6 27.6/189
MOF-20021c 4530 3.59 80 7.4/36 0.28 23.4/114
MOF-20521c 4460 2.16 80 7.0/46 NA 25.8/167
MOF-21021c 6240 3.6 80 8.6/44 NA 26.4/135
MOF-17729 4526 1.59 70 7.5/32 NA NA
NOTT-11230 3800 1.62 35 7.07/35.6 NA NA
NOTT-14022a 2620 1.07 20 6.0/41a NA 15.3c/105
UTSA-2022b 1156 0.63 15 4.1/36 NA 14d/123
PCN-1422c 1753 0.87 45 4.42/36.6 NA 18e/149
PCNP-6622d 4000 1.63 45 6.65/29.6 0.785b 17.5d/78
PCN-6822d 5109 2.13 50 7.32/28 1.01b 18.6d/71
NU-10021b 6143 2.82 70 9.95/29 NA NA
Cu-TDPA22e 1938 0.93 52 4.89/38 0.61f 16.8g/131
Mn-BTT31 2100 0.795 90 5.1/43 0.94 NA
SNU-77H22f 3670 1.52 90 8.1/47.4 0.5 17.7h/104
FJI-122g 4043 1.21 62 6.52/26.4 0.43 24.5/99
a

total uptake.

b

90 bar.

c

293 K.

d

35 bar.

e

290 K, 35 bar

f

61 bar.

g

80 bar.

h

60 bar.