Table 1.
MOF | BET Surface area (m2/g) |
Pore volume (cm3g−1) |
Pressur e (bar) |
Excess H2 uptake at 77 K (wt%)/Volumetric (g/L) |
Excess H2 uptake at 298 K (wt%) |
Excess CH4 uptake at 298 K (wt %)/Volumetric (g/L) |
---|---|---|---|---|---|---|
Zn- | ||||||
TBCPPM23 | 2718 | 1.46 | 80 | 5.8/39 | 1.6 | 27.6/189 |
MOF-20021c | 4530 | 3.59 | 80 | 7.4/36 | 0.28 | 23.4/114 |
MOF-20521c | 4460 | 2.16 | 80 | 7.0/46 | NA | 25.8/167 |
MOF-21021c | 6240 | 3.6 | 80 | 8.6/44 | NA | 26.4/135 |
MOF-17729 | 4526 | 1.59 | 70 | 7.5/32 | NA | NA |
NOTT-11230 | 3800 | 1.62 | 35 | 7.07/35.6 | NA | NA |
NOTT-14022a | 2620 | 1.07 | 20 | 6.0/41a | NA | 15.3c/105 |
UTSA-2022b | 1156 | 0.63 | 15 | 4.1/36 | NA | 14d/123 |
PCN-1422c | 1753 | 0.87 | 45 | 4.42/36.6 | NA | 18e/149 |
PCNP-6622d | 4000 | 1.63 | 45 | 6.65/29.6 | 0.785b | 17.5d/78 |
PCN-6822d | 5109 | 2.13 | 50 | 7.32/28 | 1.01b | 18.6d/71 |
NU-10021b | 6143 | 2.82 | 70 | 9.95/29 | NA | NA |
Cu-TDPA22e | 1938 | 0.93 | 52 | 4.89/38 | 0.61f | 16.8g/131 |
Mn-BTT31 | 2100 | 0.795 | 90 | 5.1/43 | 0.94 | NA |
SNU-77H22f | 3670 | 1.52 | 90 | 8.1/47.4 | 0.5 | 17.7h/104 |
FJI-122g | 4043 | 1.21 | 62 | 6.52/26.4 | 0.43 | 24.5/99 |
total uptake.
90 bar.
293 K.
35 bar.
290 K, 35 bar
61 bar.
80 bar.
60 bar.