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Solid-state structures of complexes 2–5 and 7. Top: Depictions of full molecules 2 and 7; Bottom: Truncated Mn4Ox cores. Thermal ellipsoids are drawn at 50% probability. Hydrogen atoms, outersphere anions, and solvent molecules are not shown for clarity. Bolded bonds highlight the Mn4Ox cores. See SI for detailed crystallographic information. The structure of complex 5 has been reported previously.33
