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. Author manuscript; available in PMC: 2014 Aug 23.
Published in final edited form as: J Nat Prod. 2013 Aug 14;76(8):10.1021/np400350k. doi: 10.1021/np400350k

Table 2. 13C NMR Spectroscopic Data for 16a,b.

Position 1 2 3 4 5 6
1 173.7, C 172.9, C 171.2, C 171.0, C 171.5, C 173.6, C
2 114.9, CH 116.4, CH 117.6, CH 118.0, CH 117.7, CH 115.0, CH
3 171.9, C 167.4, C 169.3, C 169.1, C 169.6, C 171.7, C
4 68.3, CH 69.6, CH 27.7, CH2 27.6, CH2 27.6, CH2 68.3, CH
5 35.4, CH2 32.4, CH2 25.1, CH2 25.5, CH2 25.5, CH2 35.4, CH2
6 117.3, CH 116.4, CH 122.2, CH 123.3, CH 122.3, CH 117.2, CH
7 141.7, C 140.7, C 137.2, C 136.2, C 137.0, C 142.0, C
8 39.7, CH2 39.7, CH2 39.6, CH2 42.2, CH2 39.4, CH2 39.8, CH2
9 26.3, CH2 26.5, CH2 26.4, CH2 126.0, CH 26.0, CH2 26.3, CH2
10 123.6, CH 123.6, CH 123.9, CH 138.0, CH 123.9, CH 122.9, CH
11 136.1, C 135.8, C 135.5, C 73.4, C 136.0, C 136.9, C
12 40.1, CH2 40.1, CH2 40.1, CH2 42.8, CH2 33.6, CH2 40.2, CH2
13 28.2, CH2 28.3, CH2 28.3, CH2 22.9, CH2 30.9, CH2 27.9, CH2
14 136.4, C 136.5, C 136.5, C 136.6, C 80.6, C 137.0, C
15 48.1, C 48.1, C 48.2, C 35.1, C 39.7, C 35.0, C
16 215.9, C 215.8, C 216.2, C 39.8, CH2 38.0, CH2 39.8, CH2
17 36.1, CH2 36.1, CH2 36.1, CH2 19.5, CH2 22.7, CH2 19.5, CH2
18 31.7, CH2 31.6, CH2 31.6, CH2 32.8, CH2 34.0, CH2 32.7, CH2
19 127.4, C 127.3, C 127.3, C 127.1, C 150.4, C 127.0, C
20 19.6, CH3 19.6, CH3 19.6, CH3 19.8, CH3 108.3, CH2 19.8, CH3
21 24.6, CH3 24.6, CH3 24.6, CH3 28.6, CH3 24.1, CH3 28.6, CH3
22 24.6, CH3 24.6, CH3 24.6, CH3 28.6, CH3 22.1, CH3 28.6, CH3
23 16.1, CH3 16.0, CH3 16.0, CH3 27.5, CH3 16.0, CH3 16.1, CH3
24 16.5, CH3 16.4, CH3 16.2, CH3 16.5, CH3 16.3, CH3 16.4, CH3
25 71.2, CH2 71.1, CH2 99.0, CH 99.0, CH 99.3, CH 71.2, CH2
4-OAc 169.8, C
20.8, CH3
a

Assignments based on HSQC and HMBC spectra.

b

Spectra were recorded in CDCl3.