Table 2. 13C NMR Spectroscopic Data for 1–6a,b.
Position | 1 | 2 | 3 | 4 | 5 | 6 |
---|---|---|---|---|---|---|
1 | 173.7, C | 172.9, C | 171.2, C | 171.0, C | 171.5, C | 173.6, C |
2 | 114.9, CH | 116.4, CH | 117.6, CH | 118.0, CH | 117.7, CH | 115.0, CH |
3 | 171.9, C | 167.4, C | 169.3, C | 169.1, C | 169.6, C | 171.7, C |
4 | 68.3, CH | 69.6, CH | 27.7, CH2 | 27.6, CH2 | 27.6, CH2 | 68.3, CH |
5 | 35.4, CH2 | 32.4, CH2 | 25.1, CH2 | 25.5, CH2 | 25.5, CH2 | 35.4, CH2 |
6 | 117.3, CH | 116.4, CH | 122.2, CH | 123.3, CH | 122.3, CH | 117.2, CH |
7 | 141.7, C | 140.7, C | 137.2, C | 136.2, C | 137.0, C | 142.0, C |
8 | 39.7, CH2 | 39.7, CH2 | 39.6, CH2 | 42.2, CH2 | 39.4, CH2 | 39.8, CH2 |
9 | 26.3, CH2 | 26.5, CH2 | 26.4, CH2 | 126.0, CH | 26.0, CH2 | 26.3, CH2 |
10 | 123.6, CH | 123.6, CH | 123.9, CH | 138.0, CH | 123.9, CH | 122.9, CH |
11 | 136.1, C | 135.8, C | 135.5, C | 73.4, C | 136.0, C | 136.9, C |
12 | 40.1, CH2 | 40.1, CH2 | 40.1, CH2 | 42.8, CH2 | 33.6, CH2 | 40.2, CH2 |
13 | 28.2, CH2 | 28.3, CH2 | 28.3, CH2 | 22.9, CH2 | 30.9, CH2 | 27.9, CH2 |
14 | 136.4, C | 136.5, C | 136.5, C | 136.6, C | 80.6, C | 137.0, C |
15 | 48.1, C | 48.1, C | 48.2, C | 35.1, C | 39.7, C | 35.0, C |
16 | 215.9, C | 215.8, C | 216.2, C | 39.8, CH2 | 38.0, CH2 | 39.8, CH2 |
17 | 36.1, CH2 | 36.1, CH2 | 36.1, CH2 | 19.5, CH2 | 22.7, CH2 | 19.5, CH2 |
18 | 31.7, CH2 | 31.6, CH2 | 31.6, CH2 | 32.8, CH2 | 34.0, CH2 | 32.7, CH2 |
19 | 127.4, C | 127.3, C | 127.3, C | 127.1, C | 150.4, C | 127.0, C |
20 | 19.6, CH3 | 19.6, CH3 | 19.6, CH3 | 19.8, CH3 | 108.3, CH2 | 19.8, CH3 |
21 | 24.6, CH3 | 24.6, CH3 | 24.6, CH3 | 28.6, CH3 | 24.1, CH3 | 28.6, CH3 |
22 | 24.6, CH3 | 24.6, CH3 | 24.6, CH3 | 28.6, CH3 | 22.1, CH3 | 28.6, CH3 |
23 | 16.1, CH3 | 16.0, CH3 | 16.0, CH3 | 27.5, CH3 | 16.0, CH3 | 16.1, CH3 |
24 | 16.5, CH3 | 16.4, CH3 | 16.2, CH3 | 16.5, CH3 | 16.3, CH3 | 16.4, CH3 |
25 | 71.2, CH2 | 71.1, CH2 | 99.0, CH | 99.0, CH | 99.3, CH | 71.2, CH2 |
4-OAc | 169.8, C | |||||
20.8, CH3 |
Assignments based on HSQC and HMBC spectra.
Spectra were recorded in CDCl3.