Figure 1. Determination of
and
from the mass spectrometric records by minimizing the sum of squared deviations.
Illustration of the fitting procedure used to determine
at a given
of 0.12 cm s−1 (A) or both
and
(B). The sum of squares of deviations between experimental concentrations of C18O16O and their counterparts from the calculated C18O16O decay curve as obtained with the fitted values of
/
are plotted vs. the value of
(A) or vs. both the values of
and
(B).