Skip to main content
. Author manuscript; available in PMC: 2014 Sep 4.
Published in final edited form as: J Am Chem Soc. 2013 Aug 23;135(35):10.1021/ja4065393. doi: 10.1021/ja4065393

Figure 1.

Figure 1

Co(acacen)(Im)2 (1) adsorbs to the PbS QD surface and PET occurs from the PbS QD to 1, increasing propensity toward axial ligand dissociation (1*). Oxidation back to Co(III) provides open coordination sites in the axial positions for the incoming ligand – here, 4MeIm – to form a mixture of three species – 1, 2, and 3 in relative abundances of 25%, 50%, and 25%, respectively.