Table 3.

Rate constants and thermodynamic parameters for the oxidation of cyclanols by QnFC: [cyclanols] = 3.0 × 10⁻² mol·dm⁻³, [QnFC] = 10.5 × 10⁻⁴ mol·dm⁻³, [H⁺] = 3.0 × 10⁻¹ mol·dm⁻³, and AcOH : H₂O = 60 : 40 (%, v/v)

Cyclanols	k 1 × 104 (s−1)				ΔH # (kJ·mol−1)	−ΔS # (J·K−1·mol−−1)	ΔG # (kJ·mol−1) at 313 K	E a (kJ·mol−1) at 313 K	r
	303 K	313 K	323 K	333 K
Cyclohexanol	9.00	12.17	17.84	25.32	26.56	186.94	94.26	29.16	0.996
Cyclopentanol	10.57	14.46	20.93	29.13	25.97	187.48	93.80	28.57	0.997
Cycloheptanol	16.8	21.98	30.76	42.23	24.46	188.92	92.72	27.06	0.998
Cyclooctanol	17.07	23.81	32.41	45.24	24.48	188.29	92.50	27.08	0.999

Error limits: ΔH ^# 25.97 ± 2 kJ·mol⁻¹, ΔS ^# −187.48 ± 4 J·K⁻¹·mol⁻¹, and ΔG ^# 93.80 ± 2 kJ·mol⁻¹ at 313 K