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. Author manuscript; available in PMC: 2014 Sep 23.
Published in final edited form as: Organometallics. 2013 Sep 23;32(18):10.1021/om4006966. doi: 10.1021/om4006966

Table 2.

Selected data for the metathesis homocoupling of 8 a

graphic file with name nihms520329t2.jpg
11
11/12e
entry cat. cat. load., mol %b solvent time, min conv, %c E/Z d
1 1a 2.5 C6H6 15 25 0.97 13
120 32 1.4 2.9
2 4 2.5 C6H6 45 24 0.97 26
120 29 1.1 19
a

All reactions were carried out using 0.005 mmol of catalyst, 0.20 mmol of 8 and 0.10 mmol of tridecane (internal standard for GC analysis) in 1.0 ml of C6H6 at 23°C.

b

Based on 8.

c

Conversion of 8 to 11 determined by GC analysis.

d

Molar ratio of E isomer and Z isomer of 11 determined by GC analysis.

e

Determined by GC analysis.