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. 2013 Oct 4;288(47):34121–34130. doi: 10.1074/jbc.M113.500637

SCHEME 2.

SCHEME 2.

Proposed mechanism for the NtdA-catalyzed half-reaction of l-glutamate. 1, internal aldimine of PLP; 2, external aldimine with l-glutamate; 3, quinoid intermediate; 4, imine of 2-oxoglutarate and PMP; 5, PMP.