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. Author manuscript; available in PMC: 2015 Sep 1.
Published in final edited form as: Combust Flame. 2014 Mar 1;161(3):766–779. doi: 10.1016/j.combustflame.2013.05.027

Table 4.

Rate coefficients of H-atom additions in the format A × Tn × exp(−E/RT). (k units: cm3, mol, s−1, kcal).

No. Reactions A n E Footnote
R167 MF + H = furan + CH3 5.82E+19 −1.61 9.7 a
R168 MF + H = CO + C4H7-v 1.19E+32 −5.24 17.0 a,b
R169 MF + H = CHO + 1,3-C4H6 1.49E+31 −5.24 17.0 a,b
a

Analogy with the reactions of DMF at low pressure.

b

Sum of pre-exponential factors of reactions R168 and R169 was taken equal to the pre-exponential factor of the reaction DMF+H=CH3CO+1,3-C4H6, while their ratio was set equal to that in the mechanism of Somers et al. [11] at low pressure and high temperature.