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. Author manuscript; available in PMC: 2013 Nov 22.
Published in final edited form as: Adv Synth Catal. 2010 Mar 20;352(5):10.1002/adsc.200900835. doi: 10.1002/adsc.200900835

Table 1.

Ag-Catalyzed olefination of aldehydes using 1-siloxy-1-propyne or 1-siloxy-1-hexyne

graphic file with name nihms448204u1.jpg
Entry R1 R2 Product Yieid, % E:Z Ratio
1 Me graphic file with name nihms448204t1.jpg 6 87 >95:5
2 Me graphic file with name nihms448204t2.jpg 7 75 >95:5
3 Me graphic file with name nihms448204t3.jpg 8 74 >95:5
4 Me graphic file with name nihms448204t4.jpg 9 75 >95:5
5 Me graphic file with name nihms448204t5.jpg 10 84 >95:5
6 n-Bu graphic file with name nihms448204t6.jpg 11 85 92:8
7 n-Bu graphic file with name nihms448204t7.jpg 12 93 94:6
8 n-Bu graphic file with name nihms448204t8.jpg 13 94 92:8
9 n-Bu graphic file with name nihms448204t9.jpg 14 66 >95:5
10 n-Bu graphic file with name nihms448204t10.jpg 15 73 83:17
11 n-Bu graphic file with name nihms448204t11.jpg 16 84 >95:5