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. Author manuscript; available in PMC: 2013 Nov 22.
Published in final edited form as: Angew Chem Int Ed Engl. 2010;49(2):10.1002/anie.200905223. doi: 10.1002/anie.200905223

Scheme 2.

Scheme 2

Synthesis of a cis- or trans-disubstituted alkene may be accomplished through hydroalumination/desilylation of a Si-substituted alkyne.