Skip to main content
. Author manuscript; available in PMC: 2014 Oct 9.
Published in final edited form as: J Am Chem Soc. 2013 Sep 24;135(40):10.1021/ja4072964. doi: 10.1021/ja4072964

Scheme 1.

Scheme 1

Design of Iron Probe 1 (IP1), a reaction-based probe for Fe2+ featuring a biomimetic, oxidative bond-cleavage reaction. IP1 contains an expanded mimic of a mononuclear non-heme 2-His-1-carboxylate coordination motif with an open sixth apical site for O2 activation.