Table 1.
Entry | Aryl acetanilide | Palladacycles | Yield (%)b |
---|---|---|---|
1 | 75 | ||
2 | 93 | ||
3 | 68 | ||
4 | 87 | ||
5 | 54 | ||
6 | 95 | ||
7 | 67 | ||
8 | 70 | ||
9 | 71 | ||
10 | 73 | ||
11 | 35 | ||
12 | 92 | ||
13 | 72 | ||
14 | 60 | ||
15 | 85c |
Reactions were carried out with 0.1 mmol acetanilide, 1 equiv Pd(OAc)2 and 1 equiv p-TsOH·H2O in 1mL dioxane at room temperature for 1-10 h.
Isolated yields.
Estimated based 1H NMR.