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Macroscopic observable rates Λi from TR crystallography. Temperature dependences are fitted by the Van’t Hoff–Arrhenius equation. The temperature dependence of process τ1 (Λ1) cannot be determined owing to limited time resolution. n.a., not applicable.
| Macroscopic rate coefficients | Λ1 | Λ2 | Λ3 | Λ4 |
|---|---|---|---|---|
| Pre-factor ν (s−1) | n.a. | 1.6 × 1014 | 1.9 × 1013 | 7.7 × 1010 |
| Energy of activation E a (kJ mol−1) | n.a. | 35.9 | 53.4 | 49.6 |
