Table 2.
Methylated sugar | Retention | Molar ratio | Mass fragment (m/z) | Type of linkage |
---|---|---|---|---|
time (min) | ||||
2,3,4,6-tetra-O-Me-Glc a | 14.80 | 1.32 | 43, 45, 71, 87, 101, 117, 129, 145, 161, 205 | Glc-(1→ |
2,4,6-tri-O-Me-Man | 16.95 | 3.16 | 43, 45, 87, 101, 117, 129, 161, 233 | →3)-Man-(1→ |
2,3,4-tri-O-Me-Glc | 17.31 | 6.43 | 43, 45, 71, 87, 101, 117, 129, 161, 173, 189, 233 | →6)-Glc-(1→ |
2,4-tri-O-Me-Man | 19.16 | 0.97 | 43, 87, 101, 117, 129, 189 | →3,6)-Man-(1→ |
a 2,3,4,6-tetra-O-Me-Glc = 1,5-di-O-acetyl-2,3,4,6-tetra-O-methyl-glucose.