Skip to main content
. 2013 Sep 26;15(19):5110–5113. doi: 10.1021/ol4024979

Table 2. APH Reductions of Ketonesa.

graphic file with name ol-2013-024979_0007.jpg

substrate catalyst t/h conv % ee %
13 4 16 100 94 (R)
13 9 16 100 84 (R)
14 4 16 70 84 (R)
17 4 24 100 91 (S)
17 9 24 94 88 (S)
22 4 24 98 >99 (R)
22 9 24 100 99 (R)
23 4 48 100 99 (R)
23 9 48 60 99 (R)
26 4 48 99 37 (S)
26 9 48 40 81 (S)
27 4 48 95 98 (R)
27 9 48 72 95 (R)
28 4 16 100 94 (R)
28 9 16 100 80 (R)
29 4 16 98 92 (R)
29 9 16 99 74 (R)
30 4 24 100 82 (R)
31 4 48 32 80 (R)
32 4 24 100 95 (S)
a

Conv % and ee % calculated as for Table 1.