Table 2.
Apparent kinetic constants with alternate substrates. a
Enzyme | Substrate | kcat (s−1) | Km (µM) | kcat/Km (M−1 s−1) | Relative kcat/Km (%) |
---|---|---|---|---|---|
MTH IPK | IPb | 27.5 ± 0.3 | 12.7 ± 0.6 | 2.2 × 106 | 100 |
ISP | 8.22 ± 0.09 | 23.7 ± 0.8 | 3.5 × 105 | 16 | |
DMAP | 34.0 ± 0.3 | 43.2 ± 1.0 | 7.9 × 105 | 36 | |
BP | 31.8 ± 0.7 | 263 ± 18 | 1.2 × 105 | 5.5 | |
BEP | 20.5 ± 0.3 | 297 ± 12 | 6.9 × 104 | 3.1 | |
GP | 0.0142 ± 0.0002 | 740 ± 43 | 19 | 0.00086 | |
THA IPK | IPb | 8.0 ± 0.2 | 4.4 ± 0.5 | 1.8 × 106 | 100 |
ISP | 2.84 ± 0.06 | 14.5 ± 1.2 | 2.0 × 105 | 11 | |
DMAP | 11.3 ± 0.4 | 174 ± 18 | 6.5 × 104 | 3.6 | |
BP | 9.9 ± 0.1 | 173 ± 7 | 5.7 × 104 | 3.2 | |
BEP | 8.07 ± 0.09 | 103 ± 5 | 7.8 × 104 | 4.3 | |
GPc | 0.047 ± 0.008 | 4700 ± 1300 | 10 | 0.00055 |
Apparent kinetic constants determined at ATP = 200 µM.
Data from reference (the characterization paper).
The highest GP concentration used was 4.5 mM.