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. Author manuscript; available in PMC: 2014 Nov 4.
Published in final edited form as: Chem Commun (Camb). 2013 Nov 4;49(85):10.1039/c3cc45000g. doi: 10.1039/c3cc45000g

Table 1.

Effective magnetic moment and dissociation of CoII complexes in D2O solutions at 37 °C.

Complex µeff[a]
µB
% Dissociation[b]
Acidic
% Dissociation[c]
Anions
[Co(1)]2+ 5.2 1 5
[Co(2)]2+ 4.5 7 2
[Co(3)]2+ 4.6 95 5
[Co(4)]2+ 4.1 16 <1
[a]

5 mM CoII complex in D2O.1a, 8

[b]

pD 3.5 – 3.9, 100 mM NaCl, 12 h incubation at 37 °C.

[c]

0.40 mM Na2HPO4, 25 mM K2CO3, 100 mM NaCl, pD 7.5 – 7.9, 12 h incubation at 37 °C.