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. Author manuscript; available in PMC: 2014 Nov 25.
Published in final edited form as: Organometallics. 2013 Nov 25;32(22):10.1021/om400651p. doi: 10.1021/om400651p

Table 2.

Borylations of 27

entry conditions yield, %
28 29 30
1 5 mol% Tf2NH, 160 °C, 14h 30a 48a 0
2 0.9 equiv Ph3C+ [B(C6F5)4], rt, 4h 29b 38b 25b
3 0.9 equiv Ph3C+ [B(C6F5)4], 60 °C, 20h 17b 4b 70b
a

Isolated yields.

b

NMR yields vs. internal reference.