. 2013 May 14;68(1):95–111. doi: 10.1007/s11418-013-0777-9

Table 2.

MSPD validation parameters for 163 active substances of four different herbs (sorted by substance group)

No.	Substance group	Active substance	Pesticide type	Detector	R ²	LOD (mg/kg)	LOQ (mg/kg)	Linden (Tilia)		Lungwort (Pulmonaria L.)		Melissa (Melissa L.)		Peppermint (Mentha piperita L.)
No.	Substance group	Active substance	Pesticide type	Detector	R ²	LOD (mg/kg)	LOQ (mg/kg)	Rec. (n = 3) (%)	RSD (%)	Rec. (n = 3) (%)	RSD (%)	Rec. (n = 3) (%)	RSD (%)	Rec. (n = 3) (%)	RSD (%)
1.	Acylalanine	Benalaxyl	F	NP	0.99986	0.010	0.020	105	8	104	8	102	2	102	4
2.	Alkanamide	Napropamide	H	NP	0.99983	0.010	0.020	95	7	99	9	105	14	100	8
3.	Amine	Diphenylamine	F	NP	0.99998	0.010	0.020	86	5	105	3	83	3	100	4
4.	Anilinopyrimidine (3)	Cyprodinil	F	NP	0.99600	0.005	0.007	105	7	103	6	106	5	107	5
5.		Mepanipyrim	F	NP	0.99994	0.010	0.020	97	6	98	10	101	2	103	3
6.		Pyrimethanil	F	NP	0.99980	0.005	0.007	84	10	96	12	99	8	97	10
7.	Aryloxyphenoxypropionate	Fluazifop-p-butyl	H	NP	0.99738	0.010	0.020	88	13	98	5	92	9	87	6
8.	Benzamide	Propyzamide	H	EC/NP	0.99998	0.010	0.020	85	5	100	6	111	8	106	7
9.	Benzilate	Bromopropylate	A	EC	0.99988	0.005	0.010	91	8	115	4	107	2	105	6
10.	Benzonitrile	Dichlobenil	H	EC/NP	0.99994	0.005	0.010	72	9	105	2	90	11	103	4
11.	Bridged diphenyl	Tetradifon	A	EC	0.99686	0.007	0.010	74	2	95	8	103	6	93	8
12.	Carbamate (7)	Carbaryl	I	NP	0.99545	0.020	0.030	70	9	103	16	96	1	91	11
13.		Carbofuran	I, A	NP	0.99876	0.010	0.020	77	6	95	10	86	3	85	9
14.		Chlorpropham	H	NP	0.99997	0.008	0.010	103	7	108	3	104	7	101	6
15.		Iprovalicarb	F	NP	0.99998	0.010	0.020	82	5	104	5	106	8	100	3
16.		Pirimicarb	I	NP	1.00000	0.005	0.008	90	6	94	9	98	10	91	7
17.		Propham	H	NP	0.99999	0.008	0.010	78	8	105	12	109	6	103	10
18.		Propoxur	I, A	NP	0.99908	0.008	0.010	80	7	92	14	101	7	92	11
19.	Carboxamide (2)	Boscalid	F	EC/NP	0.99953	0.005	0.007	83	10	96	5	97	9	89	3
20.	Carboxamide (2)	Hexythiazox	A	EC/NP	0.99976	0.030	0.040	82	5	96	2	91	8	86	5
21.	Chlorinated aromatic hydrocarbon	HCB	F	EC	0.99998	0.005	0.007	101	9	96	4	107	13	93	11
22.	Chlorinated hydrocarbon	Dieldrin	I	EC	0.99984	0.004	0.008	80	4	87	13	86	14	77	11
23.	Chloroacetamide (3)	Acetochlor	H	EC/NP	0.99996	0.010	0.015	108	9	103	5	102	7	106	6
24.		Metazachlor	H	EC/NP	0.99970	0.009	0.010	71	8	77	7	74	3	80	4
25.		Propachlor	H	EC/NP	0.99989	0.010	0.015	105	7	110	9	105	10	104	7
26.	Chloronitrile	Chlorothalonil	F	EC/NP	0.99653	0.008	0.010	89	9	85	11	95	15	100	5
27.	Chlorophenyl (5)	Dicloran	F	EC	0.99568	0.008	0.010	74	14	91	16	86	14	94	3
28.		Quintozene	F	EC	0.99942	0.004	0.006	81	4	109	15	72	11	99	2
29.		Tecnazene	F	EC	0.99743	0.005	0.009	98	2	115	2	84	4	104	5
30.		Tetrachlorvinphos	I, A	EC/NP	0.99969	0.008	0.010	92	16	92	3	91	9	96	4
31.		Tolclofos-methyl	F	EC/NP	0.99983	0.005	0.009	83	9	103	5	116	5	93	6
32.	Cyanoacetamide ozime	Cymoxanil	F	EC/NP	0.99866	0.040	0.050	98	5	108	7	96	6	102	7
33.	Cyclodiene	Aldrin	I	EC	0.99947	0.003	0.005	83	8	86	5	82	13	85	8
34.	Dicarboximide (2)	Iprodione	F	EC/NP	0.99967	0.008	0.010	108	8	101	9	115	15	99	6
35.	Dicarboximide (2)	Procymidone	F	EC/NP	0.99939	0.006	0.010	104	4	113	3	108	5	106	4
36.	Dinitroaniline (2)	Pendimethalin	H	EC/NP	0.99999	0.008	0.010	99	9	103	6	79	8	102	4
37.	Dinitroaniline (2)	Trifluralin	H	EC/NP	0.99996	0.007	0.010	108	2	101	2	99	3	100	7
38.	Diphenyl ether	Nitrofen	H	EC	0.99913	0.005	0.007	109	3	99	1	89	12	95	3
39.	Hydroxyanilide	Fenhexamid	F	EC/NP	0.99742	0.009	0.010	96	1	108	1	106	8	89	5
40.	Imidazole (3)	Fenamidone	F	EC/NP	0.99999	0.010	0.020	74	7	98	1	93	7	98	4
41.		Imazalil	F	EC	0.99254	0.009	0.010	53	3	55	12	66	4	67	8
42.		Prochloraz	F	EC/NP	0.99706	0.008	0.010	84	2	79	10	73	8	72	9
43.	Isoxazolidinone	Clomazone	H	NP	1.00000	0.020	0.030	81	8	98	5	95	4	82	6
44.	Morpholine (2)	Dimethomorph	F	NP	0.99507	0.010	0.020	80	7	100	1	93	12	97	4
45.	Morpholine (2)	Fenpropimorph	F	NP	0.99991	0.010	0.020	84	4	104	14	96	4	100	10
46.	Neonicotinoid	Acetamiprid	I	EC/NP	0.99562	0.009	0.010	48	5	51	15	45	5	55	10
47.	Organochlorine (15)	Alpha-HCH	I	EC	0.99461	0.004	0.005	96	4	93	3	92	6	87	10
48.		Beta-HCH	I	EC	0.99963	0.007	0.009	94	9	93	2	97	6	88	9
49.		Dicofol	A	EC	0.99937	0.005	0.008	107	7	105	15	114	4	118	1
50.		Endrin	I	EC	0.99934	0.004	0.005	82	1	89	3	87	2	85	8
51.		Gamma-HCH (lindane)	I, A	EC	0.99898	0.005	0.007	102	10	103	11	101	3	109	8
52.		Endosulfan-alpha	I, A	EC	0.99956	0.005	0.008	84	14	99	8	95	5	92	12
53.		Endosulfan-beta	I, A	EC	0.99794	0.005	0.008	82	6	99	3	93	9	83	5
54.		Endosulfan-sulfate	I, A	EC	0.99779	0.005	0.008	88	6	94	14	96	2	91	14
55.		Heptachlor	I	EC	0.99998	0.004	0.005	92	5	97	4	99	4	96	3
56.		Heptachlor-epoxide	I	EC	0.99997	0.004	0.005	89	2	101	7	107	2	91	16
57.		Methoxychlor (DMDT)	I	EC	0.99967	0.006	0.010	116	2	114	9	113	3	117	8
58.		op’ -DDT	I	EC	0.99989	0.004	0.005	76	2	77	5	70	9	72	3
59.		pp’ -DDD	I	EC	0.99995	0.004	0.005	86	2	94	2	95	2	90	7
60.		pp’ -DDE	I	EC	0.99890	0.003	0.004	91	14	95	8	91	9	96	6
61.		pp’ -DDT	I	EC	0.99920	0.006	0.007	71	9	75	12	80	6	73	7
62.	Organophosphate (31)	Azinphos-ethyl	I, A	EC/NP	0.99990	0.008	0.010	94	1	112	5	92	7	101	4
63.		Azinphos-methyl	I, A	EC/NP	0.99771	0.008	0.010	81	7	91	6	89	10	96	7
64.		Chlorfenvinphos	I, A	EC/NP	0.99989	0.007	0.010	85	8	109	13	94	7	99	11
65.		Chlorpyrifos	I	EC/NP	0.99964	0.005	0.007	97	8	100	10	101	8	98	6
66.		Chlorpyrifos-methyl	I, A	EC/NP	0.99999	0.005	0.007	105	7	107	8	103	5	100	5
67.		Coumaphos	I	EC/NP	0.99997	0.008	0.010	77	10	102	6	105	6	99	5
68.		Diazinon	I, A	EC/NP	0.99998	0.005	0.008	105	8	108	1	115	10	100	3
69.		Dimethoate	I, A	EC/NP	0.99999	0.008	0.010	62	8	66	2	69	4	68	3
70.		Ethion	I, A	EC/NP	0.99999	0.009	0.010	76	8	78	15	86	12	88	5
71.		Ethoprophos	I	EC/NP	0.99994	0.007	0.010	72	10	114	6	113	13	111	8
72.		Fenitrothion	I	EC/NP	0.99985	0.005	0.009	89	7	98	5	106	6	99	7
73.		Fenthion	I	NP	0.99997	0.009	0.010	58	10	63	3	54	1	66	7
74.		Heptenophos	I	NP	0.99998	0.008	0.010	78	4	87	15	96	7	83	11
75.		Isofenphos	I	EC/NP	1.00000	0.006	0.010	74	13	73	10	89	6	86	6
76.		Isofenphos-methyl	I	EC/NP	0.99992	0.006	0.010	106	9	108	2	109	16	100	3
77.		Malaoxon	I, A	NP	1.00000	0.005	0.009	92	15	103	1	108	7	98	2
78.		Malathion	I, A	EC/NP	0.99992	0.008	0.010	81	12	103	5	95	7	81	7
79.		Mecarbam	I, A	EC/NP	0.99995	0.008	0.010	88	5	85	8	97	11	87	9
80.		Methidathion	I, A	EC/NP	0.99994	0.007	0.010	81	2	102	9	98	16	92	8
81.		Paraoxon-ethyl	I	EC/NP	0.99997	0.005	0.010	74	8	74	6	90	2	84	5
82.		Paraoxon-methyl	I	EC/NP	0.99945	0.005	0.010	100	4	103	5	98	7	93	4
83.		Parathion	I, A	EC/NP	0.99932	0.008	0.010	96	6	101	10	109	10	91	11
84.		Parathion-methyl	I	EC/NP	0.99967	0.008	0.010	105	3	105	12	117	9	102	10
85.		Phorate	I, A	EC/NP	0.99995	0.009	0.010	55	4	65	13	49	8	61	11
86.		Phosalone	I, A	EC/NP	0.99981	0.007	0.010	94	7	103	5	99	13	97	10
87.		Phosmet	I, A	EC/NP	0.99987	0.009	0.010	96	3	104	8	102	7	100	6
88.		Pirimiphos-ethyl	I, A	NP	0.99999	0.005	0.008	74	4	70	1	82	3	76	2
89.		Pirimiphos-methyl	I, A	NP	0.99996	0.005	0.008	95	7	104	2	111	1	103	3
90.		Profenofos	I, A	EC/NP	0.99995	0.008	0.010	73	3	72	6	88	5	75	8
91.		Quinalphos	I, A	EC/NP	0.99608	0.005	0.006	75	1	107	3	113	16	107	5
92.		Triazophos	I, A	NP	0.99999	0.007	0.010	112	7	106	4	116	10	101	3
93.	Organothiophosphate (5)	Bromophos-ethyl	I	EC/NP	0.99956	0.005	0.007	86	5	104	8	100	14	84	9
94.		Bromophos-methyl	I	EC/NP	0.99996	0.005	0.007	93	5	104	5	97	7	94	3
95.		Fenchlorphos	I	EC/NP	0.99987	0.009	0.010	100	10	104	6	94	4	99	5
96.		Formothion	I, A	EC/NP	0.99984	0.008	0.010	68	15	58	8	65	10	59	9
97.		Methacrifos	I, A	EC/NP	0.99979	0.009	0.010	82	7	94	10	95	9	84	12
98.	Oxadiazine	Indoxacarb	I	EC/NP	0.99965	0.009	0.010	93	8	101	12	91	7	91	11
99.	Oxazole	Vinclozolin	F	EC/NP	0.99971	0.009	0.010	92	8	104	13	94	4	102	9
100.	Phenylamide (2)	Metalaxyl	F	NP	0.99986	0.008	0.010	89	9	95	5	103	5	97	4
101.	Phenylamide (2)	Oxadixyl	F	EC/NP	0.99995	0.020	0.030	70	10	75	6	77	3	71	5
102.	Phenylpyrazole	Fipronil	I	EC/NP	0.99988	0.004	0.005	84	4	83	9	92	5	83	7
103.	Phenylpyrrole	Fludioxonil	F	NP	0.99908	0.008	0.010	100	5	107	5	87	4	88	6
104.	Phosphorothiolate	Pyrazophos	F	EC/NP	1.00000	0.009	0.010	73	7	76	14	76	16	79	11
105.	Phthalimide (2)	Captan	F	EC	0.99917	0.008	0.010	59	13	68	16	50	12	67	6
106.	Phthalimide (2)	Folpet	F	EC	0.99889	0.008	0.010	69	15	64	12	56	10	59	10
107.	Pyrazole	Tebufenpyrad	A	NP	0.99998	0.009	0.010	103	11	106	9	105	8	102	6
108.	Pyrethroid (13)	Acrinathrin	I, A	EC	0.99976	0.010	0.020	106	5	96	6	108	2	98	9
109.		Alpha-cypermethrin	I	EC/NP	0.99892	0.006	0.010	93	13	99	6	100	10	95	7
110.		Beta-cyfluthrin	I	EC/NP	0.99962	0.009	0.010	86	2	101	8	99	9	88	9
111.		Bifenthrin	I, A	EC	0.99980	0.009	0.010	94	8	105	3	96	6	94	9
112.		Cyfluthrin	I	EC/NP	0.99920	0.009	0.010	74	6	94	6	96	13	93	5
113.		Cypermethrin	I	EC	0.99993	0.009	0.010	73	16	85	12	81	5	86	11
114.		Deltamethrin	I	EC/NP	0.99993	0.009	0.010	87	9	93	5	94	8	89	8
115.		Esfenvalerate	I	EC/NP	0.99044	0.008	0.010	76	5	104	3	94	11	84	4
116.		Fenpropathrin	I, A	EC/NP	0.99997	0.007	0.010	80	10	94	5	88	7	79	8
117.		Fenvalerate	I, A	EC/NP	0.99965	0.008	0.010	74	3	97	14	83	7	87	12
118.		Lambda-cyhalothrin	I	EC/NP	0.99933	0.008	0.010	77	5	94	16	74	5	92	15
119.		Permethrin	I	EC	0.99983	0.009	0.010	75	10	97	10	101	2	90	11
120.		Zeta-cypermethrin	I	EC	0.99977	0.008	0.010	97	5	98	6	102	8	96	7
121.	Pyridazinone	Pyridaben	I, A	EC/NP	0.99992	0.010	0.020	77	2	80	9	100	4	83	8
122.	Pyrimidine	Fenarimol	F	EC/NP	0.99995	0.009	0.010	76	4	85	7	88	9	81	8
123.	Pyrimidinol	Bupirimate	F	EC/NP	0.99974	0.008	0.010	88	8	97	8	118	8	97	7
124.	Quinoline	Quinoxyfen	F	EC/NP	0.99996	0.009	0.010	103	1	99	2	107	3	100	3
125.	Strobilurin (5)	Azoxystrobin	F	EC/NP	0.99960	0.009	0.010	91	6	105	5	107	7	97	4
126.		Dimoxystrobin	F	EC/NP	0.99999	0.008	0.010	78	5	92	6	92	11	96	5
127.		Kresoxim-methyl	F	EC/NP	0.99994	0.007	0.010	99	2	108	4	103	5	97	8
128.		Pyraclostrobin	F	EC/NP	1.00000	0.010	0.020	84	2	82	10	108	16	81	11
129.		Trifloxystrobin	F	EC/NP	0.99993	0.005	0.008	78	2	83	6	104	6	85	8
130.	Strobilurin type-methoxyacrylate	Picoxystrobin	F	EC/NP	0.99998	0.008	0.010	77	11	79	9	96	3	77	9
131.	Sulphamide (2)	Dichlofluanid	F	EC/NP	0.99407	0.006	0.010	77	5	98	6	74	6	89	8
132.	Sulphamide (2)	Tolylfluanid	F	EC/NP	0.99987	0.008	0.010	76	2	89	1	74	2	99	2
133.	Triazine (3)	Atrazine	H	NP	1.00000	0.007	0.010	107	7	100	5	96	1	103	6
134.		Prometrine	H	NP	0.99998	0.009	0.010	72	3	104	6	93	2	84	9
135.		Simazine	H	NP	0.99999	0.006	0.010	77	8	101	5	113	1	91	7
136.	Triazinone	Metribuzin	H	EC/NP	0.99979	0.008	0.010	76	8	96	2	81	2	94	3
137.	Triazole (21)	Azaconazole	F	EC/NP	0.99995	0.009	0.010	73	8	78	2	81	5	82	4
138.		Biterthanol	F	NP	0.99959	0.009	0.010	103	3	104	5	75	5	77	5
139.		Cyproconazole	F	EC/NP	0.99999	0.009	0.010	97	8	103	6	101	3	90	8
140.		Difenoconazole	F	EC/NP	0.99996	0.008	0.010	75	7	72	3	77	8	72	4
141.		Diniconazole	F	EC/NP	0.99972	0.007	0.010	86	1	87	6	110	11	87	5
142.		Epoxiconazole	F	EC/NP	0.99999	0.009	0.010	96	10	90	5	111	2	95	6
143.		Fenbuconazole	F	NP	0.99976	0.009	0.010	90	5	91	7	98	4	95	5
144.		Fluquinconazole	F	EC/NP	0.99975	0.009	0.010	74	8	75	6	106	5	87	7
145.		Flusilazole	F	NP	0.99985	0.007	0.010	78	1	107	3	115	9	102	6
146.		Flutriafol	F	EC/NP	0.99994	0.009	0.010	71	3	88	4	86	10	76	5
147.		Hexaconazole	F	EC/NP	0.99971	0.006	0.010	100	9	104	5	92	8	101	3
148.		Imibenconazole	F	EC/NP	0.99990	0.008	0.010	87	10	86	6	98	3	84	9
149.		Metconazole	F	NP	0.99993	0.008	0.010	95	7	105	8	93	5	90	9
150.		Myclobutanyl	F	EC/NP	0.99992	0.009	0.010	101	9	106	10	109	4	103	11
151.		Paclobutrazol	F	EC/NP	0.99995	0.015	0.020	94	4	110	5	114	8	101	6
152.		Penconazole	F	EC/NP	0.99946	0.009	0.010	95	6	109	6	104	8	91	7
153.		Propiconazole	F	EC/NP	0.99977	0.008	0.010	92	8	99	4	105	5	94	8
154.		Tebuconazole	F	NP	0.99990	0.007	0.010	100	9	103	2	110	7	109	3
155.		Tetraconazole	F	EC/NP	0.99987	0.008	0.010	101	4	102	6	106	8	100	7
156.		Triadimefon	F	EC/NP	0.99998	0.008	0.010	88	6	90	4	92	5	95	5
157.		Triadimenol	F	EC/NP	1.00000	0.009	0.010	106	11	106	6	105	11	101	7
158.	Triazole (isomer mix)	Bromuconazole	F	EC/NP	0.99996	0.008	0.010	97	13	104	2	93	8	91	3
159.	Unclassified (4)	Fenazaquin	A, I	NP	0.99990	0.010	0.015	102	5	100	2	102	3	104	3
160.		Buprofezin	I,A	EC/NP	0.99995	0.008	0.009	81	2	85	5	88	8	85	6
161.		DEET	I	NP	0.99999	0.015	0.020	106	4	106	6	100	9	106	7
162.		Pyriproxyfen	I	NP	0.99995	0.020	0.025	73	11	78	5	71	10	78	6
163.	Uracyl	Lenacil	H	NP	0.99998	0.010	0.020	74	5	75	4	76	4	75	5

Pesticides in bold have recovery below 70 % (values in italics)

A acaricide, F fungicide, H herbicide, I insecticide, EC electron capture, NP nitrogen phosphorus, R ² correlation coefficient, RSD relative standard deviation, Rec. mean recovery