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. Author manuscript; available in PMC: 2013 Dec 14.
Published in final edited form as: Tetrahedron. 2012 Jun 19;68(37):10.1016/j.tet.2012.06.036. doi: 10.1016/j.tet.2012.06.036

Scheme 1.

Scheme 1

Compounds studied in this paper. The mechanism for conversion of NH2–Cam (1) to chloramphenicol (4) by CmlI is given above. Solid lines indicate reactions catalyzed by CmlI, and dashed lines indicate a spontaneous nonenzymatic oxidation.