Table 5.

Pd-catalyzed C–H trifluoromethylation employing Umemoto’s sulfonium tetrafluoroborate salt [67].

Product		Yield (%)a	Product	Yield (%)a
		86		0c
		82		88
	2-Me 3-Me 4-Me	84 83 83		75c
	2-OMe 3-OMe 4-OMe	78 54b 68		58c
	2-Cl 3-Cl 4-Cl	55c 75c 72c		62c
		78b		53c
		87b		74
		88

^aYields for isolated compounds. ^b15 mol % of Pd(OAc)₂ were used. ^c20 mol % of Pd(OAc)₂ were used.