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. Author manuscript; available in PMC: 2013 Dec 21.
Published in final edited form as: J Am Chem Soc. 2007 May 27;129(24):10.1021/ja072528a. doi: 10.1021/ja072528a

Figure 2.

Figure 2

4.2-K Mössbauer spectra of MnIV/FeIII-R2 derived by component analysis of the experimental spectra. The solid lines are simulations according to the spin Hamiltonian given in the Supporting Information and the following parameters: STotal = 1, DS=1 = −1.9 cm−1, (E/D)S=1 = 0.33, δ = 0.52 mm/s, ΔEQ = 1.32 mm/s, η = −2.6, (A/gNβN)Fe = (−40.2, −38.9, −38.0) T.