Table 2. PRE Data, Correlation Times (τc), PRE Effects, and PRE Derived and Predicted Distances of RNAs 3, 5, 6, and 6ARG.
RNA IDa | residueb | PRE 1H-Γ2, s–1c | correlation time (τc), nsd | distance (PRE), Åe | distance (predicted), Åf |
---|---|---|---|---|---|
3 | A3 | 30.46 ± 1.51 | 3.2 | 13.2 ± 0.1 | 12.6 |
C7 | 4.38 ± 0.79 | 18.3 ± 0.6 | 22.5 | ||
A8 | 5.04 ± 0.78 | 17.7 ± 0.5 | 18.1 | ||
U12 | 5.45 ± 0.82 | 17.6 ± 0.5 | 17.8 | ||
5 | C15a | 37.22 ± 2.83 | g | h | g |
C15b | 2.24 ± 2.78 | h | g | ||
6 | C19 | 18.29 ± 2.39 | 4.71 | 15.29 ± 0.34 | 15.71 ± 1.30 |
C24 | h | 3.69 | h | 29.32 ± 2.91 | |
C29 | h | 4.54 | h | 28.22 ± 4.76 | |
C33 | 2.67 ± 1.52 | 4.63 | 22.31 ± 4.42 | 34.05 ± 3.34 | |
C37 | 2.25 ± 1.36 | 4.34 | 23.11 ± 4.52 | 27.10 ± 4.39 | |
C39 | 3.94 ± 2.13 | 5.22 | 21.21 ± 4.40 | 19.97 ± 4.07 | |
C41 | 6.77 ± 2.51 | 5.27 | 18.97 ± 1.83 | 19.54 ± 3.17 | |
C44 | 14.80 ± 2.27 | 4.48 | 15.69 ± 0.37 | 17.84 ± 2.34 | |
6ARG | C19 | 14.26 ± 2.16 | 4.64 | 15.92 ± 0.43 | 15.61 ± 1.49 |
C24 | 0.93 ± 0.68 | 3.07 | 25.55 ± 5.12 | 31.76 ± 2.72 | |
C29 | h | 4.87 | h | 29.61 ± 4.07 | |
C33 | h | 4.62 | h | 34.49 ± 3.23 | |
C37 | h | 5.07 | h | 25.71 ± 3.91 | |
C39 | 10.87 ± 2.60 | 5.05 | 16.96 ± 0.75 | 19.73 ± 3.63 | |
C41 | 5.51 ± 2.85 | 4.73 | 19.82 ± 3.98 | 19.27 ± 3.17 | |
C44 | 8.28 ± 2.14 | 5.65 | 18.11 ± 0.90 | 17.79 ± 2.36 |
RNA identifier.
A = adenosine; C = cytidine; U = uridine.
Paramagnetic relaxation enhancement effect determined as the difference between proton transverse relaxation rate from RNAs with and without TEMPO tag or by radical reduction using ascorbic acid (6ARG).
Correlation time estimates from HydroPro NMR3 or from 13C R1 and R1ρ relaxation measurements (6 and 6ARG);
PRE derived distance.
Distances from structural model3 or from molecular dynamic runs (6 and 6ARG).
Not available.
Not determined. Values with PRE error of 100% and more are considered insignificant and were not determined.