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. Author manuscript; available in PMC: 2015 Jan 1.
Published in final edited form as: Chem Sci. 2013 Oct 15;5(1):10.1039/C3SC52487F. doi: 10.1039/C3SC52487F

Scheme 3.

Scheme 3

(Top) Reactivity of iron(I) complexes with N2; (Bottom) Structures of the nitrogen complex K2[LFeNNFeL] (N), which is formally diiron(0), and the phenoxide complex [KLFe(OPh)2]2 (P), which is formally diiron(II)