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Key bond lengths and angles in M, D, and an iron(II) analogue
| M | D | LFeOTol | |
|---|---|---|---|
| Fe-O (Å) | 1.9220(9) | 1.929(2) | 1.833(2) |
| Fe-N (Å) | 1.913(1), 1.926(1) | 1.926(2), 1.936(2) | 1.965(2), 1.972(2) |
| N-C (Å) | 1.356(2), 1.368(2) | 1.344(3), 1.352(2) | 1.342(3), 1.335(3) |
| K-OAr (Å) | 2.609(1) | 2.586(2) | |
| K-OEt2 (Å) | 2.726(1), 2.753(1) | ||
| N-Fe-N (°) | 100.92(4) | 98.09(9) | 94.76(8) |
| N-Fe-O (°) | 142.28(4), 116.80(4) | 139.61(8), 122.28(8) | 140.20(8), 125.01(9) |
| Fe-O-C (°) | 133.13(8) | 132.5(2) | 138.8(2) |
