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. Author manuscript; available in PMC: 2014 Jun 12.
Published in final edited form as: J Am Chem Soc. 2013 Jun 3;135(23):10.1021/ja3104632. doi: 10.1021/ja3104632

Figure 8.

Figure 8

A. Schematic of oxidation within a porous thin film, illustrating the same ratio of oxidized to reduced MnOx for both thick and thin catalytic layers. B. Schematic of oxidation within a dense thin film, illustrating a higher ratio of oxidized to reduced MnOx for a thinner film. The porous structure is consistent with XANES measurements presented in Figure 6C.