. Author manuscript; available in PMC: 2013 Dec 31.

Published in final edited form as: Inorg Chem. 2008 May 23;47(13):10.1021/ic800048e. doi: 10.1021/ic800048e

Table 3. Selected Spectroscopic and Electrochemical Results for the Fe^IIIOH Complexes.

	[Fe^IIIH₃buea(OH)]⁻	[Fe^IIIH₂2^iPr(OH)]⁻	[Fe^IIIH1^iPr(OH)]⁻	[Fe^III0^iPr(OH)]⁻
ν(¹⁶O–H) (cm⁻¹)	3632^a	3668	3676	3690
λ_max (ε, mM⁻¹ cm⁻¹)	398 (4.7)^a	376 (5.3)	374 (5.3)	346 (5.4)
D, E/D (cm⁻¹)	−1.3, 0.17^a	−1.3, 0.11	−1.3, 0.16	−1.3, 0.15
E_1/2, E_pc(V)^b	−1.93 (−2.03)	−1.89 (−2.00)	−1.88 (−1.94)	c (−1.94)
ΔE_p (V)^b	0.20	0.14	0.16
i_pai_pc⁻¹^b	1.07	0.67	0.61

From ref #.

Measured as DMF solutions using [Cp₂Fe]^0/+1 as the reference.

Irreversible processes.

Table 3. Selected Spectroscopic and Electrochemical Results for the FeIIIOH Complexes.