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. Author manuscript; available in PMC: 2014 Nov 13.
Published in final edited form as: J Am Chem Soc. 2013 Nov 4;135(45):10.1021/ja408073m. doi: 10.1021/ja408073m

Scheme 1.

Scheme 1

Generic representations of: (a) HAT where the H is transferred along with its electron, and (b) PCET, where the proton H+ and electron (e) are transferred to different locations.